Unique coordination of pyrazine in T[Ni(CN)4]· 2pyzwith T = Mn, Zn,Cd

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Título :	Unique coordination of pyrazine in T[Ni(CN)4]· 2pyzwith T = Mn, Zn,Cd
Palabras clave :	Layered compounds Pillared solids
Fecha de publicación :	16-ene-2013
Editorial :	ELSEVIER
Descripción :	The materials under study, T[Ni(CN)4]·2pyz with T = Mn, Zn, Cd, were prepared by separation of T[Ni(CN)4] layers in citrate aqueous solution to allow the intercalation of the pyrazine molecules. The obtained solids were characterized from chemical analyses, X-ray diffraction, infrared,Raman, thermogravimetry, UV–Vis,magnetic and adsorption data.Their crystal structure was solved from ab initio using direct methods and then refined by the Rietveld method. A unique coordination for pyrazine to metal centers at neighboring layers was observed. The pyrazine molecule is found forming a bridge between Ni and T atoms, quite different from the proposed structures for T = Fe, Ni where it remains coordinated to two T atoms to form a vertical pillar between neighboring layers. The coordination of pyrazine to both Ni and T atoms minimizes the material free volume and leads to form a hydrophobic framework. On heating the solids remain stable up to140 ºC. No CO2 and H2 adsorption was observed in the small free spaces of their frameworks.
URI :	http://www.repositoriodigital.ipn.mx/handle/123456789/10699
Otros identificadores :	J SOLID STATE CHEM 182 (2009) 757-766 0022-4596 http://hdl.handle.net/123456789/182
Aparece en las colecciones:	Doctorado

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09 JSSC Lemus-Santana Unique Coord.pdf		1.27 MB	Adobe PDF	Visualizar/Abrir

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