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Título : | Transformation of cadmium ferricyanide by heating, milling and sonication |
Palabras clave : | cadmium ferricyanide reducing agen reducing agent ecomposition |
Fecha de publicación : | 16-ene-2013 |
Editorial : | Elsevier Science Ltd |
Descripción : | On heating, milling and sonication, cadmium ferricyanide decomposes and reduces to cadmium ferrocyanide. Two compositions were studied, pure cadmium ferricyanide and mixed potassium cadmium ferricyanide. The role of reducing agent is played by the CN anions liberated during the decomposition process. The solid decomposition product is composed by several phases of cadmium ferrocyanide, an Fe ~ phase and also potassium ferrocyanide in the case of the mixed complex salt. The decomposition process was monitored using DTA, XRD, IR and M6ssbauer techniques. No occurrence of linkage isomerization in cadmium ferricyanide was detected. 1998 Elsevier Science Ltd. All rights reserved Kevwords: ; : d. |
URI : | http://www.repositoriodigital.ipn.mx/handle/123456789/11716 |
Otros identificadores : | PM.vheeb'on Vol. 17. Nos 13 14, pp, 2353 2361. 1998 http://hdl.handle.net/123456789/1255 |
Aparece en las colecciones: | Doctorado |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
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1998PolyFe3Cd 1.pdf | 77.24 kB | Adobe PDF | Visualizar/Abrir |
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