Por favor, use este identificador para citar o enlazar este ítem: http://repositoriodigital.ipn.mx/handle/123456789/11694
Título : Mechanochemical synthesis of hemin±imidazole complexes
Fecha de publicación : 16-ene-2013
Editorial : Transition Metal Chemistry
Descripción : Solid state reactions of hemin and imidazole were performed by milling the crystalline materials in an agate mortar. The process was monitored by i.r., x.r.d. and MoÈ ssbauer spectroscopies. Samples with di erent hemin to imidazole molar ratios were studied. The interactions of imidazole with the central Fe atom and with the propionic acid groups in the periphery of the hemin molecule were detected. The latter interactions are suppressed by washing with MeOH. Complexes with 1:2 and 1:4 hemin-to-imidazole molar ratios were identi®ed.
URI : http://www.repositoriodigital.ipn.mx/handle/123456789/11694
Otros identificadores : Transition Metal Chemistry 26: 76±80, 2001.
http://hdl.handle.net/123456789/1233
Aparece en las colecciones: Doctorado

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