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http://repositoriodigital.ipn.mx/handle/123456789/11534Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | REGUERA, E. | - |
| dc.creator | BALMASEDA, J. | - |
| dc.creator | RODRIGUEZ HERNANDEZ, J. | - |
| dc.date | 2012-03-29T02:10:29Z | - |
| dc.date | 2012-03-29T02:10:29Z | - |
| dc.date | 2004-05-28 | - |
| dc.date.accessioned | 2013-01-16T16:02:57Z | - |
| dc.date.available | 2013-01-16T16:02:57Z | - |
| dc.date.issued | 2013-01-16 | - |
| dc.identifier | Journal of Porous Materials 11: 219–228, 2004 | - |
| dc.identifier | http://hdl.handle.net/123456789/1090 | - |
| dc.identifier.uri | http://www.repositoriodigital.ipn.mx/handle/123456789/11534 | - |
| dc.description | The behavior of microporous nitroprussides in the presence of ammonia, both in anhydrous and hydrated states,was studied using ammonia adsorption isotherms and IR,M¨ossbauer and XRD techniques. In their anhydrous state these materials behave as a zeolite for ammonia adsorption, however when structural water is present a decomposition process was observed. The crystallization or adsorbed water is used by ammonia to form NH+ 4 and OH−, creating basic conditions where the structural building unit [Fe(CN)5NO] loses the NO group to form a pentacyano complex. This leads to the formation of mixed salts, M(NH4)[Fe(CN)5]·xH2O. For ferrous nitroprusside the formed OH− ion competes with the complex anion for the iron(2+) cation which is removed, then oxidized and finally observed as a ferric oxyhydroxide, FeOOH. | - |
| dc.language | en | - |
| dc.publisher | Journal of Porous Materials | - |
| dc.subject | adsorption | - |
| dc.subject | infrared | - |
| dc.subject | microporous | - |
| dc.subject | nitroprusside | - |
| dc.subject | pentacyanide | - |
| dc.subject | ammonia | - |
| dc.subject | M¨ossbauer | - |
| dc.title | Behavior of Microporous Nitroprussides in Presence of Ammonia | - |
| dc.type | Article | - |
| Aparece en las colecciones: | Doctorado | |
Ficheros en este ítem:
| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| 2004NPsNH3 1.pdf | 33.16 kB | Adobe PDF | Visualizar/Abrir |
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