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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.creator | Tzompantzi, F. | - |
dc.creator | Manriquez, M. | - |
dc.creator | Padilla, J.M. | - |
dc.creator | Del Angel, G. | - |
dc.creator | Gomez, R. | - |
dc.creator | Mantilla, A. | - |
dc.date | 2012-03-14T03:06:34Z | - |
dc.date | 2012-03-14T03:06:34Z | - |
dc.date | 2008-01-31 | - |
dc.date.accessioned | 2013-01-16T08:27:40Z | - |
dc.date.available | 2013-01-16T08:27:40Z | - |
dc.date.issued | 2013-01-16 | - |
dc.identifier | Catalysis Today 133–135 (2008) 154–159 | - |
dc.identifier | 9205861 | - |
dc.identifier | http://hdl.handle.net/123456789/75 | - |
dc.identifier.uri | http://www.repositoriodigital.ipn.mx/handle/123456789/10612 | - |
dc.description | The synthesis of NiO/ZrO2 sulfated catalysts prepared by the one pot method (sol–gel) is reported. Specific surface areas comprised between 52 and 108 m2/g were obtained. XRD patterns showed the presence of monoclinic and tetragonal zirconia phases. FTIR-pyridine absorption spectra show the presence of Lewis and Bro¨nsted sites in sulfated zirconia but only Lewis sites in nickel zirconia sulfated catalysts. A good correlation between the amount of adsorbed pyridine and the catalytic activity for the isopropanol dehydration was observed. However, an opposite effect was observed for the isobutene oligomerization, where the catalysts with the lower acidity showed the higher activity. The role of Ni+2 diminishing the deactivation rate forming p-allylic bonds with the olefins is discussed. | - |
dc.description | Se sintetizaron catalizadores de NiO/ZrO2 sulfatado con acidez controlada para la oligomerización de butenos. Se discute el efecto de la presencia del Ni+2 en la estabilidad del catalizador. | - |
dc.description | Instituto Politecnico Nacional, CONACYT | - |
dc.language | en | - |
dc.publisher | Catalysis Today | - |
dc.subject | Oligomerización | - |
dc.subject | Gasolinas alto octano | - |
dc.subject | NiO/ZrO2 sulfatado | - |
dc.subject | Catalizadores de acidez controlada | - |
dc.title | One pot preparation of NiO/ZrO2 sulfated catalysts and its evaluation for the isobutene oligomerization | - |
dc.type | Article | - |
Aparece en las colecciones: | Doctorado |
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Fichero | Descripción | Tamaño | Formato | |
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One pot preparation of NiOZrO2 sulfated catalysts and its evaluation for the isobutene oligomerization 1a hoja.pdf | 73.84 kB | Adobe PDF | Visualizar/Abrir |
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