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dc.creatorTzompantzi, F.-
dc.creatorValverde Herrera, M.-
dc.creatorRodriguez Gonzalez, J.-
dc.creatorGomez, R.-
dc.creatorMantilla, A.-
dc.creatorFernandez, J.L.-
dc.date2012-03-14T02:48:25Z-
dc.date2012-03-14T02:48:25Z-
dc.date2009-10-10-
dc.date.accessioned2013-01-16T08:26:39Z-
dc.date.available2013-01-16T08:26:39Z-
dc.date.issued2013-01-16-
dc.identifierChem.Eng.Comm.-
dc.identifier986445-
dc.identifierhttp://hdl.handle.net/123456789/73-
dc.identifier.urihttp://www.repositoriodigital.ipn.mx/handle/123456789/10610-
dc.descriptionIsobutene oligomerization on W2O3/Al2O3 and NiO-W2O3/Al2O3 catalysts (20 wt.% W2O3 and 5 wt.% NiO) was studied. The catalysts were prepared by impregnating ammonium tungstanate and nickel nitrate on a E-alumina sol-gel support. The XRD patterns of the samples calcined at 500°C show the presence of large W2O3 conglomerates on the W2O3/Al2O3 sample and smaller ones on the NiO-W2O3/Al2O3 catalyst. Pyridine-FT-IR absorption spectra study shows a higher acidity on the nickel-containing sample. The isobutene oligomerization was carried out in a gas-phase flow reactor (50°-150°C), and selectivity as high as 100% to the formation of the olefins fraction was obtained. The role of NiO coordinating the J-allyl adsorption of the olefins as well as its role to the high selectivity were discussed.-
dc.descriptionSe reportan los resultados de la oligomerización de butenos para obtención de gasolinas de alto octano mediante catalizadores de alumina W2O3 con y sin la presencia de Ni.-
dc.descriptionInstituto Politecnico Nacional, CONACYT-
dc.languageen-
dc.publisherChemical Engineering Communications-
dc.subjectOligomerización-
dc.subjectGasolinas alto octano-
dc.subjectCatálisis ácida-
dc.subjectNiO-W2O3/Al2O3-
dc.titleImproved selectivity to C8-Olefins for isobutene oligomerization on NiO-W2O3/Al2O3 catalysts-
dc.typeArticle-
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